Na'vi eyes are physically proportionally larger than ours, which means a greater light gathering ability, as well as better visual acuity, as large eyes are linked to better visual acuity among species on Earth. While Pandora has much bioluminescence and reflected light from its gas giant parent, it is also a very densely forested world with a dense, humid and very cloudy atmosphere. Tropical forests are quite dark, shadowy places, so though it may never be as dark as on Earth, it's also likely true that it's rarely, if ever, as bright either.
I suspect this would mean that Na'vi sight has evolved to being good at colour differentiation in gloomy but not dark conditions, instead of excellent night vision, as they rely heavily on spotting and identifying fruits and berries in the jungle. Bioluminescence also puts out light in specific wavelengths, making good colour sensitivity important. So my guess is they see a similar range of colours to us, but are much better at retaining full colour sensitivity in twilight/gloomy conditions when humans begin to lose colour perception, but that true night vision no better, and probably worse all round. I suspect their movement sensitivity is better, due to the need to detect threats and prey in subdued light in dense vegetation, though probably not by much.